Required practical: Priya investigates the relationship between the striking (threshold) voltage of light-emitting diodes (LEDs) and the wavelength of light they emit, in order to determine an approximate value for the Planck constant. Her circuit connects an LED in series with a variable resistor, a milliammeter and a low-voltage d.c. supply, with a voltmeter connected across the LED. She increases the p.d. across the LED slowly from zero until it just begins to emit light (the striking voltage, V). At the striking voltage, assume that all of the electrical energy gained by an electron passing through the LED converts into the energy of a single emitted photon, so that eV = hc/λ, where λ is the wavelength of the emitted light. Her results for four LEDs are: Red, λ = 660 nm, V = 1.62 V; Yellow, λ = 590 nm, V = 1.82 V; Green, λ = 525 nm, V = 2.15 V; Blue, λ = 470 nm, V = 2.45 V. e = 1.60 x 10-19 C, c = 3.00 x 108 m/s.
(a)Explain why the circuit must include a variable resistor connected in series with the LED, rather than connecting the LED directly across the supply.(2)
(b)Describe how Priya should determine the striking voltage of each LED, and suggest one precaution she should take to improve the precision of this reading.(3)
(c)Show that the equation eV = hc/λ can be rearranged to give V = (hc/e) x (1/λ), and explain how a graph could be used with this equation to determine a value for the Planck constant, h.(3)
(d)Calculate the value of 1/λ, in m-1, for the green LED (λ = 525 nm).(1)
(e)The graph of V against 1/λ for Priya's four data points has a gradient of 1.26 x 10-6 V m. Use this gradient to calculate a value for the Planck constant, h.(3)
(f)The accepted value of the Planck constant is 6.63 x 10-34 Js. Calculate the percentage difference between Priya's value (from part e) and the accepted value.(2)
(g)Suggest one reason, other than random error in judging the striking voltage, why Priya's experimental value of h might differ systematically from the accepted value.(1)
(h)Identify one variable that Priya should keep constant across all four LEDs to ensure a fair comparison of striking voltages.(1)
(Total for Question 9 is 16 marks)