Life Cycle Assessment, Recycling and Corrosion
Life cycle assessment, recycling and corrosion cover the four stages of a life cycle assessment, the reasons recycling and reusing materials reduces environmental impact, and corrosion, the destruction of a material, particularly a metal, by reaction with substances in its environment. Rusting of iron needs both oxygen and water, and can be slowed by barrier methods such as paint or electroplating, or by sacrificial protection, in which a more reactive metal corrodes in place of iron.
Before you start
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Method
- Break a life cycle assessment into its four stages and identify the impacts considered at each: extracting and processing raw materials (energy used, resources consumed, waste and pollution produced); manufacturing and packaging the product (energy and water used, waste generated); using the product over its lifetime (energy, water or consumables it uses while in service); and disposal at the end of its life (whether it can be reused, recycled, or must go to landfill or be incinerated, and the impact of each option).
- Recognise that life cycle assessments can be selective and are not always fully objective, since some impacts, such as the effect on habitats or the value of a scarce resource, are hard to quantify numerically, and a study funded by an interested party may emphasise the stages that favour its own product; independently produced or verified assessments are more reliable.
- Explain why recycling materials, particularly metals, reduces environmental impact: recycling avoids the energy-intensive steps of mining and extracting new metal from ore, so it typically uses far less energy than producing the same mass of new metal, while also conserving limited ore reserves and reducing the volume of waste sent to landfill.
- Define corrosion as the gradual destruction of a material by chemical reaction with substances in its environment, and identify rusting as the specific name for the corrosion of iron; state, from the classic experiment (an iron nail rusts in a tube of water open to air, but not in boiled, oxygen-free water sealed under a layer of oil, and not in dry air over a drying agent), that rusting needs both oxygen and water to be present together.
- Explain how barrier methods prevent corrosion: coatings such as paint, oil, grease or electroplating with another metal work by physically excluding oxygen and water from reaching the surface of the metal underneath, so no reaction can occur while the coating remains intact.
- Explain sacrificial protection using the reactivity series: attaching a block of a more reactive metal, such as zinc or magnesium, to iron or steel means the more reactive metal loses electrons and corrodes (is oxidised) in preference to the iron, protecting the iron for as long as any of the more reactive metal remains; galvanising, coating iron with a layer of zinc, combines this sacrificial effect with a physical barrier.
- Explain why most everyday metal objects are made from alloys rather than pure metals: mixing a metal with one or more other elements introduces atoms of a different size into the regular layered structure of the metal, which distorts the layers and makes it harder for them to slide over one another, so most alloys are harder than the pure metal alone; name examples such as bronze (copper and tin), brass (copper and zinc), and steels (iron with carbon, and often other metals such as chromium and nickel in stainless steel).
Worked example
A student sets up three test tubes to investigate what causes iron nails to rust. Tube 1 contains a nail in water open to the air. Tube 2 contains a nail in boiled, cooled water, with a layer of oil on top of the water. Tube 3 contains a nail surrounded by dry air, with a drying agent (anhydrous calcium chloride) in the tube, which is then sealed. After a week, the nail in Tube 1 has rusted but the nails in Tubes 2 and 3 have not. Explain what this experiment shows about the conditions needed for rusting.
- Identify what each tube tests: Tube 1 has both oxygen (from the air) and water present; Tube 2 has water but very little dissolved oxygen (removed by boiling) and the oil layer stops more oxygen from the air dissolving in; Tube 3 has oxygen (dry air) but the drying agent removes any water vapour, so no water is present.
- Interpret Tube 1 rusting: since both oxygen and water were present together, rusting occurred.
- Interpret Tube 2 not rusting: oxygen was excluded from the water by boiling and the oil seal, so even with water present, no rusting occurred.
- Interpret Tube 3 not rusting: water was excluded by the drying agent, so even with oxygen present, no rusting occurred.
- Final answer: rusting only occurs when both oxygen and water are present together; if either one is missing, iron does not rust, which is confirmed by comparing all three tubes.
Practice questions
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Q1State the four stages considered in a life cycle assessment.Show answer
Answer: Extracting and processing raw materials, manufacturing and packaging, use, and disposal at the end of the product's life.
Q2Give one reason a manufacturer's own life cycle assessment of its product might not be fully objective.Show answer
Answer: It may emphasise the stages or impacts that make its own product look most favourable, or leave out impacts that are difficult to measure, so an independently produced assessment is more trustworthy.
Q3State the two substances that must both be present for iron to rust.Show answer
Answer: Oxygen and water.
Q4Explain how painting an iron gate helps prevent it from rusting.Show answer
Answer: The paint forms a physical barrier that stops oxygen and water in the air from reaching the surface of the iron, so the reaction that causes rusting cannot take place while the coating remains intact.
Q5Explain, using the reactivity series, why attaching blocks of zinc to the hull of a steel ship helps prevent the steel from rusting.Show answer
Answer: Zinc is more reactive than iron, so the zinc loses electrons and corrodes (is oxidised) in preference to the iron, sacrificially protecting the steel hull for as long as zinc remains attached.
Q6Explain why steel (an alloy of iron and carbon) is generally harder than pure iron.Show answer
Answer: The carbon atoms are a different size from the iron atoms, so they distort the regular layers of iron atoms, making it harder for the layers to slide over each other than in pure iron, which increases the hardness of the alloy.
Q7State one environmental benefit of recycling aluminium cans rather than making new aluminium from ore.Show answer
Answer: Recycling aluminium uses far less energy than extracting new aluminium from its ore by electrolysis, and it conserves limited supplies of aluminium ore and reduces the volume of waste sent to landfill.
Exam-style questions
Written in the style of a GCSE Science exam paper, with a full mark scheme.
A car manufacturer is deciding whether to make a car body panel from new steel or from recycled steel. Using ideas from life cycle assessment, explain the environmental advantages of using recycled steel over each of the four stages of the panel's life, and explain why the choice of material at the manufacturing stage particularly affects the environmental impact of the extraction stage.
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A steel water pipe buried underground is protected from rusting by connecting it to a block of magnesium, which is replaced periodically. Explain how this method protects the pipe, and name this method of corrosion prevention.
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Free printable worksheet
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This topic is chapter 31 of GCSE Chemistry Workbook, the whole course as one free printable PDF.
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